birdseye:the simplest way to bring out the eyes, (artists do this with portraits) use the burn tool, set at about 45%, , and add highlights on top of the small highlights that are there on the eyeball itself....and burn in the white area of the eyeball itself, more at the bottom of the eyeball, and less as it recedes under the top eyelid.. experiment with amount of burn, until you are happy with it... this leaves the rest of the photo alone...normally i would sample the black of the pupil, and paint in one circle over top the existing pupil, and burn in the highlights or reflections afterward...play with it, and you will see how effective this is. good luck.. nice photo ...
That is one way to do it but it isn't the simplest way.
If you was to send a portrait off to a retoucher they would charge you big bucks and this is the way they do it
1. Load image into Photoshop
2. Add a curves adjument layer
3. Push the curves to brighten the image (over brighten)
4. Invert the resulting mask from the adjustment
5. Paint the eyes with white then you can back off the effect using the opacity slider.
Here are some images showin what I mean just change the ending /adjustment-1.jpg to /adjustment-2.jpg and so on up to adjustment-5.jpg
http://thekiwi.org/adjustment/adjustment-1.jpg
My New Avatar is in memory of Nancy my darling wife of 10 years who passed away on Monday November the 16th 2009 after an illness
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